Automatic title case turns API ACCESS FOR iPhone USERS into Api Access For Iphone Users. It capitalizes the first letter of every word and lowercases the rest, so acronyms and brand names lose their spelling. Use it as a first pass, then fix those words by hand.

API ACCESS FOR iPhone USERS into Input Text.Api Access For Iphone Users.API Access for iPhone Users
Capitalized Words only raises the first letter of each word and leaves the rest as it was. On mixed-case input it keeps acronyms, but it still changes brand names that start lowercase:

So on an all-caps headline it does nothing useful. On a sentence like api access for iPhone users it gives Api Access For IPhone Users. Neither mode knows your acronym list.
For a batch of headlines, keep a short list of the acronyms that recur on your site and scan for them after converting.
e-mail as one word, giving E-mail, but don't also stays one word. Read hyphenated words once.Conversion happens in your browser. Open the free Case Converter.